Superphosphate (SSP, Single Superphosphate) is the first commercial phosphorus fertilizer ever produced, developed in the mid-19th century.
It is made by treating phosphate rock with sulfuric acid (H₂SO₄), producing a mixture of monocalcium phosphate [Ca(H₂PO₄)₂] and gypsum (CaSO₄·2H₂O).
SSP typically contains 16–20% P₂O₅ in water-soluble form, along with valuable secondary nutrients like calcium and sulfur, making it a multi-nutrient fertilizer.
Field Crops: Especially effective for oilseeds, pulses, wheat, maize, and sugarcane.
Sulfur-Loving Crops: Crucial for crops like onion, garlic, mustard, and legumes that require sulfur.
Soil Conditioner: Provides calcium and sulfur in addition to phosphorus.
Direct Application or Blending: Used as a straight fertilizer or as a raw material in blends.
Raw material for producing other phosphate fertilizers.
Feed supplements (after processing).
Multi-Nutrient Supply: Provides phosphorus, calcium, and sulfur simultaneously.
Cost-Effective: Lower price compared with TSP, MAP, and DAP.
Soil Amendment: Improves soil structure with added gypsum.
Suitable for Sulfur-Deficient Soils: Corrects dual nutrient deficiencies.
Property | Value |
---|---|
Chemical Name | Single Superphosphate (SSP) |
Formula | Ca(H₂PO₄)₂ + 2CaSO₄ |
P₂O₅ Content | 16–20% (water-soluble) |
Calcium (Ca) | 18–21% |
Sulfur (S) | 10–12% |
Appearance | Gray to brown granular or powder |
Granule Size | 2–4 mm (granular SSP) |
Moisture | ≤ 3% |
Shelf Life | 12–24 months (dry storage) |
Q1: How is SSP different from TSP?
A1: SSP has 16–20% P₂O₅ while TSP has 44–48% P₂O₅. SSP also provides sulfur and calcium, whereas TSP is almost pure phosphorus.
Q2: Which crops benefit most from SSP?
A2: Oilseeds, legumes, onion, garlic, and crops grown in sulfur-deficient soils.
Q3: How should SSP be applied?
A3: Typically applied at planting in bands near the seed or broadcast and incorporated into soil.
Q4: Is SSP suitable for acidic soils?
A4: Yes, but continuous use may slightly increase soil acidity due to the presence of gypsum.
Q5: Why is SSP still used when TSP, DAP, and MAP exist?
A5: Because SSP is cheaper and provides multiple nutrients (P, S, Ca) in one application.