Dimethoate: A Broad-Spectrum Organophosphate Insecticide

2025-08-21 10:35

Technical Introduction

Dimethoate (IUPAC: O,O-dimethyl S-[2-(methylamino)-2-oxoethyl] dithiophosphate) is a broad-spectrum organophosphate insecticide and acaricide. It has been widely used in agriculture since the 1960s to control both chewing and sucking insect pests.

  • Mode of Action: Dimethoate inhibits acetylcholinesterase (AChE), an essential enzyme in the insect nervous system. This leads to accumulation of acetylcholine, causing continuous nerve impulses, paralysis, and death.

  • Systemicity: It is both contact and systemic, moving through plant tissues to protect foliage, stems, and new growth.

  • Target Spectrum: Controls a wide range of sap-sucking insects (aphids, thrips, whiteflies, leafhoppers) as well as mites.


Applications

  • Field Crops: Used in cotton, wheat, rice, soybean, and maize to manage aphids, leafhoppers, and thrips.

  • Vegetables & Fruits: Applied to tomato, potato, citrus, apple, pear, and grape crops for aphid and whitefly control.

  • Ornamental Plants: Protects against sap-feeding insects in greenhouses and landscape ornamentals.

  • Acaricidal Use: Effective against certain mite species on crops and horticultural plants.


Advantages

  • Dual Action: Works as both a contact insecticide and a systemic agent.

  • Broad-Spectrum: Effective against numerous insect pests across crop groups.

  • Cost-Effective: Relatively low production cost compared to newer insecticides.

  • Fast-Acting: Quickly reduces pest pressure after application.


Specifications (Typical Parameters)

ParameterDescriptionTypical Value
Chemical NameDimethoate
Chemical ClassOrganophosphate insecticide
Chemical FormulaC₅H₁₂NO₃PS₂
Molecular Weight~229.3 g/mol
AppearanceColorless to amber liquid
Purity (TC)≥ 95%
Common FormulationsEC (emulsifiable concentrate), WP (wettable powder), ULV (ultra-low volume concentrate)40% EC, 50% EC
Mode of ActionAcetylcholinesterase inhibitor
Target PestsAphids, whiteflies, thrips, leafhoppers, mites
Residual ActivityModerate (5–10 days)
ToxicityModerate mammalian toxicity (oral LD₅₀ in rats ~150–400 mg/kg); highly toxic to bees, aquatic life, and beneficial insects

FAQ

Q1: Is Dimethoate systemic?
A: Yes, it is both systemic and contact-active, making it effective against pests feeding on internal plant tissues.

Q2: Is Dimethoate safe for pollinators?
A: No. Dimethoate is highly toxic to bees and should not be applied during flowering or when pollinators are active.

Q3: What are the resistance risks with Dimethoate?
A: Resistance has developed in some aphid and whitefly populations due to long-term use. It is recommended to rotate with other insecticide classes (IRAC groups).

Q4: Is Dimethoate still widely used?
A: While still in use in many countries, Dimethoate is restricted or banned in the EU and some other regions due to environmental and human safety concerns.

Q5: How does Dimethoate compare with other organophosphates?
A: It has relatively lower mammalian toxicity than some older organophosphates (like parathion), but its environmental impact remains significant.

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