Penoxsulam: A Modern Herbicide for Rice Weed Management

2025-08-22 10:09

Technical Introduction

Penoxsulam (IUPAC: 2-(2,2-difluoroethoxy)-6-(trifluoromethyl)-N-(5,8-dimethoxy[1,2,4]triazolo[1,5-c]pyrimidin-2-yl)-benzenesulfonamide) is a systemic, post-emergence herbicide belonging to the triazolopyrimidine sulfonamide class.

It works by inhibiting acetolactate synthase (ALS/AHAS), an enzyme essential for the biosynthesis of branched-chain amino acids (valine, leucine, and isoleucine). This leads to growth inhibition and eventual death of susceptible weeds.

  • Mode of Action: ALS inhibitor (HRAC Group B).

  • Systemicity: Rapidly absorbed by foliage and roots, translocated throughout the plant.

  • Selectivity: Specifically designed for rice (both transplanted and direct-seeded).


Applications

  • Primary Crop:

    • Rice (both paddy and direct-seeded systems).

  • Target Weeds:

    • Controls a wide spectrum of annual grasses, sedges, and broadleaf weeds, including:

      • Echinochloa crus-galli (barnyardgrass)

      • Fimbristylis miliacea (sedge)

      • Cyperus difformis (smallflower umbrella sedge)

      • Monochoria vaginalis (pickerelweed)

      • Ludwigia spp. (water primrose)

  • Timing:

    • Applied early post-emergence when weeds are young and actively growing.

  • Formulation Use:

    • Available as OD (oil dispersion) or SC (suspension concentrate).


Advantages

  • Broad Spectrum: Controls grasses, sedges, and broadleaves with a single application.

  • Crop Safety: Selective for rice at recommended doses.

  • Low Use Rate: Effective at very low dosages compared to older herbicides.

  • Environmental Benefits: Lower application volume reduces chemical load in the field.

  • Resistance Management Tool: Alternative to ACCase inhibitors and synthetic auxins in rice.


Specifications (Typical Parameters)

ParameterDescriptionTypical Value
Chemical NamePenoxsulam
Chemical ClassTriazolopyrimidine sulfonamide
Chemical FormulaC₁₆H₁₄F₅N₅O₅S
Molecular Weight~483.37 g/mol
AppearanceOff-white solid
Purity (TC)≥ 95%
Common Formulations21.7% OD, 25% SC, 98% TC
Mode of ActionALS inhibitor (systemic)
Target WeedsGrasses, sedges, broadleaf weeds
Residual Activity2–4 weeks (depending on soil and water conditions)
ToxicityOral LD₅₀ in rats > 5,000 mg/kg (low mammalian toxicity); slightly toxic to fish & aquatic plants

FAQ

Q1: What is Penoxsulam mainly used for?
A: It is primarily used in rice cultivation to control grasses, sedges, and broadleaf weeds.

Q2: How is Penoxsulam applied?
A: Typically applied as a post-emergence foliar spray when weeds are in their early growth stages.

Q3: Does Penoxsulam have residual activity?
A: Yes, it provides 2–4 weeks of residual control, depending on soil type and water management.

Q4: Can Penoxsulam be tank-mixed with other herbicides?
A: Yes, it is often mixed with bispyribac-sodium, pyrazosulfuron-ethyl, or butachlor to broaden the weed control spectrum and manage resistance.

Q5: What is the typical application rate?
A: Generally 15–40 g a.i./ha, depending on crop stage, weed density, and formulation.

Q6: Is Penoxsulam safe for the environment?
A: It is considered environmentally favorable due to low use rates, but caution is advised in aquatic ecosystems.

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