Oxadiazon is a pre-emergence, contact-type herbicide belonging to the oxadiazole chemical class. It is primarily used to control annual grasses and broadleaf weeds in rice paddies, turfgrass, ornamental crops, and non-crop areas.
Mode of Action (MOA): Inhibits protoporphyrinogen oxidase (PPO), an enzyme in chlorophyll and heme biosynthesis. This causes accumulation of toxic intermediates that lead to cell membrane destruction upon light exposure.
Characteristics:
Acts mainly in the soil layer, preventing weed emergence.
Provides long-lasting control due to low solubility and persistence in soil.
Limited systemic activity (non-translocated).
Crops:
Rice (paddy fields) – widely used for barnyardgrass and sedges.
Turfgrass – for weed-free lawns, golf courses, and sod production.
Ornamental plants, fruit orchards, vineyards – safe for established plants.
Weeds Controlled:
Grasses: Echinochloa crus-galli (barnyardgrass), Digitaria spp., Setaria spp.
Broadleaves: Amaranthus spp., Chenopodium album, Portulaca oleracea
Sedges: Cyperus spp.
Application Timing:
Applied before weed emergence (0–5 days after transplanting in rice, or pre-sowing in turf/ornamentals).
Requires moist soil or irrigation for activation.
Strong Pre-Emergence Control: Effective against both grasses and broadleaf weeds.
Long Residual Effect: Controls weeds for 6–8 weeks.
Crop Safety: Well tolerated in rice, turf, and ornamentals.
Low Leaching: Minimal movement in soil due to low water solubility, reducing groundwater contamination risk.
Resistance Management: Useful in PPO-inhibitor herbicide programs, though rotation is still advised.
Parameter | Description | Typical Value |
---|---|---|
Common Name | Oxadiazon | |
Chemical Class | Oxadiazole herbicide (PPO inhibitor) | |
Chemical Formula | C₁₅H₁₈Cl₂N₂O₃ | |
Molecular Weight | ~345.2 g/mol | |
Appearance | Brown crystalline solid | |
Purity (TC) | ≥ 95% | |
Common Formulations | 95% TC, 50% EC, 25% SC, 2–10% GR | |
Application Rate | 0.5 – 1.5 kg a.i./ha (depending on crop) | |
Mode of Action | PPO inhibition → membrane disruption | |
Persistence | 6–8 weeks in soil (low mobility) | |
Toxicity | Oral LD₅₀ (rat) > 5,000 mg/kg (very low) |
Q1: How does Oxadiazon differ from Butachlor or Pretilachlor in rice?
A: Unlike chloroacetamides (Butachlor, Pretilachlor) that inhibit lipid biosynthesis, Oxadiazon acts via PPO inhibition, making it a good rotation partner to delay resistance.
Q2: Can Oxadiazon be used post-emergence?
A: No, it is strictly a pre-emergence herbicide and ineffective once weeds have emerged.
Q3: How long does it protect rice from weeds?
A: Provides 6–8 weeks of weed control, covering the critical early growth stage of rice.
Q4: Is Oxadiazon safe for turfgrass?
A: Yes, it is widely used in lawns, golf courses, and sod farms to maintain weed-free turf.
Q5: Is there a risk of resistance?
A: PPO-inhibitor resistance has been reported in some regions, so rotation with other herbicide classes is recommended.