Introduction to Clodinafop-Propargyl
Clodinafop-propargyl is a post-emergent, selective herbicide designed to control grass weeds in cereal crops, particularly wheat and barley. Belonging to the aryloxyphenoxypropionate (AOPP) chemical group, it is highly effective against annual grasses without damaging broadleaf crops. It is primarily used in wheat-growing regions worldwide to manage resistant weed species.
Chemical Characteristics and Mode of Action
With the molecular formula C₁₇H₁₃ClFNO₄, Clodinafop-propargyl acts by inhibiting the enzyme acetyl-CoA carboxylase (ACCase), which is essential in fatty acid synthesis for cell membrane development in grasses. This action disrupts cell growth in susceptible weeds, leading to chlorosis, necrosis, and eventual plant death. The herbicide is quickly absorbed by leaves and translocated to growing points.
Target Weeds and Crop Applications
Clodinafop-propargyl is highly effective against key annual grassy weeds such as Avena fatua (wild oats), Phalaris minor (canary grass), and Lolium rigidum (rigid ryegrass). It is commonly applied in wheat fields during early to mid-post-emergence growth stages. The herbicide offers crop safety and minimal residual impact, making it suitable for rotational farming.
Advantages of Clodinafop-Propargyl
Selective control: Targets grass weeds without affecting the cereal crop.
Fast absorption: Quick uptake and movement within the plant for efficient action.
Flexible timing: Effective in early post-emergence applications.
Tank-mix compatible: Can be mixed with broadleaf herbicides for wider spectrum control.
Improved yield potential: Reduces weed competition and enhances crop productivity.
Application Techniques and Recommendations
It is usually formulated as an emulsifiable concentrate (EC) and applied via foliar spray. The recommended dosage typically ranges from 60–90 g active ingredient per hectare, depending on weed pressure and crop conditions. An adjuvant or surfactant is often added to improve leaf penetration. Application during active weed growth and favorable weather conditions enhances performance.
Environmental and Safety Considerations
Clodinafop-propargyl has low persistence in soil and is relatively immobile, reducing groundwater contamination risk. It poses low toxicity to mammals, birds, and aquatic life when used properly. However, users must follow protective measures to avoid skin and eye contact. Resistance management is essential to preserve its effectiveness, including alternating with herbicides from different classes.
Resistance Concerns and Management
Repeated use can lead to the development of herbicide-resistant grass weed populations. The mechanism of resistance typically involves target-site mutations in the ACCase gene. To combat this, integrated weed management (IWM) strategies are encouraged, including crop rotation, herbicide rotation, mechanical weeding, and delayed sowing practices.
FAQ About Clodinafop-Propargyl
Q1: Can Clodinafop-propargyl be used in rice or maize fields?
No, it is primarily designed for cereal crops like wheat and barley. Using it in rice or maize can harm those crops due to lack of selectivity.
Q2: How long after spraying can I irrigate the field?
It is advisable to wait at least 6 hours after application before irrigation to ensure adequate absorption.
Q3: Is there a risk of crop injury if overdosed?
Yes, excessive dosage or incorrect application timing can lead to phytotoxicity in the crop. Always follow label instructions.
Q4: Does it control broadleaf weeds?
No, it is ineffective against broadleaf species. It should be mixed with compatible broadleaf herbicides for full-spectrum weed control.
Q5: What is the re-entry interval (REI) after spraying?
The REI is usually 24 hours, during which human activity in treated areas should be limited unless wearing protective equipment.